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RESEARCH COMMUNICATION PORTAL

새글 논문 해외 국제전문학술지(SCI급) (공동) Post-combustion CO2 capture of methyl and nitro mixed-linker CAU-10

논문 초록 (Abstract)

Methyl‑ and nitro‑group‑co‑functionalized CAU‑10, namely CAU‑10‑CH3‑NO2, was synthesized and compared with mono‑functionalized CAU‑10 derivatives, CAU‑10‑CH3 and CAU‑10‑NO2, as a  CO2 adsorbent. In this study, we report that methyl and/or nitro groups could increase  CO2 performance compared to that of bare CAU‑10. It is supposed that the hydrophobic character of the methyl group might support selective  CO2 uptake in humid conditions. Breakthrough experiments demonstrate that CAU‑10‑CH3‑NO2, which is more hydrophobic than CAU‑10‑NO2, reduced the degradation of adsorption performance under dry conditions. CAU‑10‑CH3‑NO2 was considered a candidate suitable for an actual post‑combustion  CO2 adsorption process.