논문 해외 국제전문학술지(SCI급) Mesopore Wall-Catalyzed Friedel–Crafts Acylation of Bulky Aromatic Compounds in MFI Zeolite Nanosponge
- 학술지 구분 국제전문학술지(SCI급)
- 게재년월 2015-04
- 저자명 Kim, J.-C., Cho, K., Lee, S., and Ryoo, R.*
- 학술지명 Catalysis Today
- 발행처명 Elsevier
- 발행국가 해외
- 논문언어 외국어
- 전체저자수 4
- 원문 링크 https://www.sciencedirect.com/science/article/abs/pii/S0920586114005975
홈페이지논문 초록 (Abstract)
We investigated the effects of mesopore generation in a MFI zeolite when used as a catalyst in liquid-phase Friedel–Crafts acylation reactions of bulky aromatic compounds. For this investigation, we obtained an MFI zeolite with nanosponge morphology, following a seed-assisted hydrothermal synthesis route using C22H45–N+(CH3)2–C6H12–N+(CH3)2–C6H13. The zeolite nanosponge exhibited a narrow distribution of mesopore diameters centered at 4 nm, in which the mesopores were built with a disordered network of 2.5-nm thick MFI zeolite layers. This zeolite exhibited high catalytic performance in various acylation reactions, compared with bulk MFI zeolites, beta zeolite and mesoporous materials composed of amorphous aluminosilicates. The high catalytic performance corresponded to the strong Brönsted acid sites existing on the mesopore walls.